Spray a 9x13 inch baking pan with cooking spray and preheat oven to 350°F.
In a large bowl, whisk together flour, sugar, cocoa powder, baking powder, baking soda, cinnamon, cayenne pepper, and salt until evenly combined.
In a stand mixer bowl, combine buttermilk, vegetable oil, eggs, and vanilla extract on medium speed until smooth.
With mixer on low speed, slowly add the dry ingredients to the wet ingredients in three additions, mixing just until combined between each addition.
Pour in the hot coffee and mix until the batter is smooth, about 30 seconds. The batter will be very thin.
Pour batter into prepared pan and bake for 30 to 35 minutes until the center springs back when touched or a toothpick inserted in the center comes out with moist crumbs.
Cool the cake completely on a wire rack, about 1 hour, before frosting.
In a stand mixer, whip the butter alone on medium speed for 2 minutes until fluffy, almost white in appearance.
Add vanilla extract and cinnamon, mixing until just combined.
Add powdered sugar slowly, about 1 cup at a time, mixing on low speed between each addition.
Alternate adding the last bit of powdered sugar with the heavy cream, 1 tablespoon at a time. If frosting is too thick after 5 tablespoons, add the sixth tablespoon.
Whip frosting on high speed for at least 2 minutes until light and fluffy.
Spread frosting over cooled cake using an offset spatula. Sprinkle mini chocolate chips over the top.