Prep Slow Cooker and Bread: Grease your 6-quart slow cooker insert with nonstick cooking spray or butter. If using fresh bread, cube it and bake at 250°F for 10 minutes to dry out. Place cubed bread and pecans (if using) in the slow cooker.
Make Custard Mixture: In a large bowl, whisk 8 eggs until combined. Add 3 cups milk, 1/4 cup maple syrup, 1 tablespoon vanilla, 2 teaspoons cinnamon, 1/2 teaspoon nutmeg, and 1 teaspoon salt. Whisk vigorously for 1 minute until smooth.
Combine and Soak: Pour custard mixture over bread cubes in slow cooker, coating evenly. Gently press bread into liquid. Let sit 15 minutes minimum, or cover and refrigerate overnight for best results.
Add Topping: In a small bowl, mix 1/2 cup brown sugar with 1 teaspoon cinnamon. Sprinkle evenly over soaked bread. Distribute butter pieces evenly across the top.
Cook: If refrigerated overnight, let insert sit at room temperature 30-45 minutes before cooking. Cover slow cooker with lid and cook on LOW for 3-4 hours or HIGH for 2-2.5 hours, until center is set and edges pull away slightly.
Rest and Serve: Turn off slow cooker and let rest 10 minutes with lid on. Scoop portions onto plates and serve with warm maple syrup, powdered sugar, fresh berries, or whipped cream.